- Numbers in parentheses indicate the length of the match.
- (c) refers to the champion(s) heading into the match.
- The Miz (w/ Brooke , Kelly Kelly & Layla) defeated Tommy Dreamer (3:32)
- Matt Striker (w/ Big Daddy V) defeated Nunzio
- Mike Knox defeated Balls Mahoney (2:02)
- CM Punk & Stevie Richards defeated Elijah Burke & Kevin Thorn (7:18)
- Featured an opening in-ring segment in which Armando Estrada introduced CM Punk as the new ECW World Champion; after Estrada told Punk he was a big fan, Punk gave him an autographed T-shirt and then pressured him to put on the shirt to prove he truly was a fan; moments later, Elijah Burke appeared with Estrada announcing Burke would face Punk Sunday at Unforgiven; after the two traded words, Burke began shoving Punk until Punk landed an enzuiguri which knocked Burke to the floor;
- Included a vignette of Big Daddy V to promote his bout the following week against the Boogeyman
- Featured a backstage segment in which Balls Mahoney gave Kelly Kelly a stuffed animal
- Included a video package highlighting Punk's title win the previous week:
- ECW on Sci Fi #66
- [ ECW #66 on WWE Network]
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