SHIMMER Women Athletes Volume 6 was the sixth SHIMMER event to be recorded by SHIMMER Women Athletes, the event took place on May 21, 2006 at the Eagles Club in Berwyn, Illinois. This was the second of two events recorded, the first event being the previous volume SHIMMER Women Athletes Volume 5.
Numbers in parentheses indicate the length of the match.
- Amazing Kong, Lexie Fyfe & Malia Hosaka defeated Ariel, Cindy Rogers & Josie (16:48)
- Serena defeated Amber O'Neal (7:28)
- Nikki Roxx defeated Lorelei Lee (8:58)
- Daizee Haze defeated Nikita (11:42)
- Rebecca Knox defeated Allison Danger in a Pure Wrestling Rules Match (25:47)
- Minnesota Home Wrecking Crew (Lacey & Rain) defeated Mercedes Martinez & Sara Del Rey (15:56)
- MsChif defeated Cheerleader Melissa in a Last Woman Standing Match (20:27)