SHIMMER Women Athletes Volume 4 was the forth SHIMMER event to be recorded by SHIMMER Women Athletes, the event took place on February 12, 2006 at the Berwyn Eagles Club in Berwyn, Illinois. This was the second of two events recorded, the first event being the previous volume SHIMMER Women Athletes Volume 3.
Numbers in parentheses indicate the length of the match.
- Nikki Roxx defeated Amber O'Neal (9:21)
- Shantelle Taylor defeated Ann Brookstone (5:53)
- Lexie Fyfe & Malia Hosaka defeated Cindy Rogers & Lorelei Lee (16:02)
- Allison Danger defeated Tiana Ringer (13:43)
- Cheerleader Melissa defeated MsChif in a Falls Count Anywhere Match (26:20)
- Sara Del Rey defeated Rain (14:06)
- Daizee Haze defeated Rebecca Knox (20:13)